Cationic β-Scission of C–H and C–C Bonds for Selective Dimerization and Subsequent Sulfur-Free RAFT Polymerization of α-Methylstyrene and Isobutylene
T. Tanimoto, M. Uchiyama, and M. Kamigaito,
Angew. Chem. Ind. Ed., 54, e202307791 (2023). [Front Cover]
Synfacts ("Sulfur-Free Cationic RAFT")
Direct Radical Copolymerizations of Thioamides to Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbone
H. Watanabe and M. Kamigaito,
J. Am. Chem. Soc., 145, 10948-10953 (2023). [Supplementary Cover] [Open Access]
Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals
M. Uchiyama, Y. Murakami, K. Satoh, and M. Kamigaito,
Angew. Chem. Int. Ed., 53, e202215021 (2023). [Hot Paper] [Inside Cover] [Open Access]
Radical-Promoted Single-Unit Monomer Insertion (SUMI) [aka. Reversible-Deactivation Radical Addition (RDRA)]
C. Boyer, M. Kamigaito, K. Satoh, G. Moad,
Prog. Polym. Sci., 138, 101648 (2023). [Open Access]
DOI: 10.1016/j.progpolymsci.2023.101648
逐次ラジカル重合ーラジカル重付加、重縮合、付加縮合
上垣外正己
監修：澤本光男
編集委員：上垣外正己、高田十志和、辻井敬亘、松本章一
pp. 641-664
エヌ・ティー・エス、2023
